A difficult one, there is a fair chance a wild cam would make the car fail an emission test, assuming you need the CAT for an MOT test (what year is the car?) you will face a stiffer emissions test anyway. 3rd party performance cams usually have more overlap and duration, and while this aids breathing once the revs rise, they do tend to make an engine produce more CO and hydrocarbons at idle (and often across whole rev range).
It might be a case of suck it and see, if it fails, you can quite often get garages to go soft on emissions, especially if you can persuade them any high emissions are a result of the cam and any other mods you have, and not a tired and/or badly tuned engine. Approach a garage before hand and speak with them, for advice. You could even go for a crypton tune and study the exhaust results from that. Also get car well warmed up, give it a decent thrash, as this quite often drops the emissions for a while. Worst comes to the worst, get an adjustable fuel regulator (power boost valve),and keep turning it down a little at a time until it scrapes through the emissions test, dont let it run lean though. Dont know if any of that helps, but I prefer typing stuff on the forum than actually doing any work. Anybody else use this forum from work?
Alex M
ps just clicked that the trick with adjustable fuel regulator probably does not work on 16v as ECU would adjust the fuel according to lambda sensor in the exhaust - sorry (is this correct?)